Energy Equation:
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The energy equation ΔE = q + w represents the first law of thermodynamics, where the change in internal energy of a system equals the heat added to the system plus the work done on the system.
The calculator uses the energy equation:
Where:
Explanation: This fundamental equation expresses conservation of energy in thermodynamic systems, accounting for both heat transfer and mechanical work.
Details: Accurate energy calculations are crucial for understanding chemical reactions, predicting reaction spontaneity, designing energy systems, and analyzing thermodynamic processes in various scientific and engineering applications.
Tips: Enter heat (q) and work (w) values in joules. Both values can be positive or negative depending on the direction of energy transfer (positive when added to the system, negative when removed from the system).
Q1: What's the difference between heat and work?
A: Heat is energy transfer due to temperature difference, while work is energy transfer due to force acting through a distance.
Q2: Can ΔE be negative?
A: Yes, ΔE is negative when the system loses more energy than it gains, indicating a net decrease in internal energy.
Q3: How does this relate to enthalpy?
A: At constant pressure, the heat transfer q equals the enthalpy change ΔH, making ΔE = ΔH + w (where w is non-PV work).
Q4: What are typical units for these calculations?
A: While joules are standard, calories are sometimes used (1 cal = 4.184 J). The calculator uses joules for consistency with SI units.
Q5: When is this equation most applicable?
A: This equation applies to closed systems where mass doesn't cross boundaries, but energy can be transferred as heat or work.