Energy Equation:
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The energy equation (ΔE = q + w) calculates the change in internal energy of a chemical system, where q represents heat transfer and w represents work done on or by the system.
The calculator uses the energy equation:
Where:
Explanation: This fundamental equation from thermodynamics states that the change in a system's internal energy equals the heat added to the system plus the work done on the system.
Details: Accurate energy change calculation is crucial for understanding thermodynamic processes, predicting reaction spontaneity, and analyzing energy conservation in chemical systems.
Tips: Enter heat transfer (q) and work (w) values in joules. Both values can be positive or negative depending on energy flow direction.
Q1: What do positive and negative values mean?
A: Positive q indicates heat added to system, negative q indicates heat released. Positive w indicates work done on system, negative w indicates work done by system.
Q2: How is this different from enthalpy?
A: Enthalpy (H) relates to heat at constant pressure, while internal energy (E) is more fundamental and applies to all systems.
Q3: When is this equation most applicable?
A: This equation applies to closed systems where only heat and work can transfer energy across boundaries.
Q4: Are there limitations to this equation?
A: The equation assumes no mass transfer and may need modification for open systems or systems with significant kinetic/potential energy changes.
Q5: What are typical units used?
A: While joules are standard, calories or other energy units can be used with proper conversion factors.