Energy Equation:
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The energy equation (ΔE = q + w) represents the first law of thermodynamics, calculating the change in internal energy of a system. It states that the change in internal energy equals the heat added to the system plus the work done on the system.
The calculator uses the energy equation:
Where:
Explanation: This fundamental equation in thermodynamics describes energy conservation in chemical systems, accounting for both heat transfer and mechanical work.
Details: Calculating energy changes is crucial for understanding chemical reactions, predicting reaction spontaneity, designing energy systems, and analyzing thermodynamic processes in chemistry and engineering.
Tips: Enter heat (q) and work (w) values in joules. Positive values indicate energy added to the system, negative values indicate energy removed from the system.
Q1: What's the difference between q and w?
A: q represents heat energy transferred due to temperature difference, while w represents mechanical work done on or by the system.
Q2: When is ΔE positive vs negative?
A: ΔE is positive when the system gains energy (endothermic), and negative when the system loses energy (exothermic).
Q3: How does this relate to enthalpy?
A: At constant pressure, the enthalpy change (ΔH) equals the heat transfer (q), making ΔE = ΔH + w for constant pressure processes.
Q4: What are typical units for these values?
A: While joules are standard, calories are sometimes used (1 cal = 4.184 J). The calculator uses joules for consistency.
Q5: Can this equation be used for all systems?
A: This equation applies to closed systems. For open systems where matter is exchanged, additional terms are needed.