Internal Energy Equation:
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The internal energy equation (ΔU = q + w) represents the first law of thermodynamics, stating that the change in internal energy of a system equals the heat added to the system plus the work done on the system.
The calculator uses the internal energy equation:
Where:
Explanation: This fundamental equation of thermodynamics shows that the internal energy of a system changes through heat transfer and work interactions with its surroundings.
Details: Calculating internal energy changes is essential for understanding thermodynamic processes, analyzing energy conservation in closed systems, and predicting system behavior in various engineering and scientific applications.
Tips: Enter heat (q) and work (w) values in joules. Positive values indicate energy added to the system, while negative values indicate energy removed from the system.
Q1: What is the sign convention for q and w?
A: Positive q indicates heat added to the system; positive w indicates work done on the system. Negative values indicate the opposite.
Q2: How does this relate to the first law of thermodynamics?
A: This equation is the mathematical statement of the first law of thermodynamics for closed systems.
Q3: What are typical units for internal energy?
A: The SI unit is joules (J), though calories or other energy units may be used with appropriate conversion factors.
Q4: Does this equation apply to all systems?
A: This form applies specifically to closed systems where only heat and work can cross the system boundary.
Q5: How is internal energy different from enthalpy?
A: Enthalpy (H) includes both internal energy and the product of pressure and volume (H = U + PV), making it more useful for constant-pressure processes.